Advanced photonics journal of applied remote sensing. A quantum derivation of the shape of the resonant transmittance peak for the general case is presented and then we analyze the effect of. Nanoporous silicon microcavity based fuel adulteration. Reflectance measurements are used to detect the concentration of kerosene, which is the most commonly used adulterant for petrol and diesel, in the fuel sample. Impact of thermal oxidation on the structural and optical. Porous silicon psi structure is used as support material to detect protein infiltration and to induce fluorescence and second harmonic light enhancement from glucose oxidase gox. The pl appearance is attributed to electronic confinement in columnarlike or dotlike structures of porous silicon. The properties and preliminar applications of porous silicon psi microcavities are here reported. Apr, 2008 porous silicon dielectric multilayers and microcavities l.
Porous silicon based bragg reflect ors and fabryperot. It was found that the critical condition for deep polymer in. Pdf nearfield spectroscopy of porous silicon microcavity. This was a novel result to the best of our knowledge. Osa a vapor sensor based on a porous silicon microcavity. Metal nanoparticles npspsimc enhanced fluorescence substrates were prepared by the electrostatic adherence of au nps that were distributed in psimc.
Fabrication of a silicon wafer to create a porous silicon microcavity psmc has been used to increase the surface area for the immune reaction and hence the probability of the dengue virus detection after chemical modification with adhesives and biofunctionalization is high by the treatment of antibody and antigen. The obtained enhancement was due to the coupling of the laser radiation and stokes photons of porous silicon with the microcavity mode at the optimal laser beam incidence and scattering. In this chapter, the porous silicon formation process in explained. The result suggests that a porous silicon microcavity can be a tool to study the dynamics of gas penetration into porous silicon since it allows a monitoring of the depth reached by the ethanol at. Exposure of the porous silicon microcavity containing entrapped polymer. Porous silicon dielectric multilayers and microcavities. We report the structural and optical characterization of onedimensional porous silicon microcavities. A quantum derivation of the shape of the resonant transmittance peak for the general case is. Porous silicon multilayer mirrors and microcavity resonators. Vertical hybrid microcavity based on a polymer layer. Taking advantage of the optical properties of porous silicon microcavity, the refractive index changes caused by biological reaction can be detected by measuring the incident angle of the minimum reflected light intensity.
Smart bandage a hydrogel supported optical microcavity. The photonic properties of porous silicon resonant microcavity psirm afford an excellent opportunity to be developed as a highly sensitive optical biosensor to monitor the presence of specific biomarkers found in the wound exudate, such as matrix metalloproteinases mmps. Spectrometerfree biological detection method using porous. Raman scattering enhancement in porous silicon microcavity. A 1d photonic porous silicon microcavity 1dppsm has been formed by electrochemical etching of highly doped ptype silicon wafers resistivity is 0. Mar 20, 2017 among porous silicon biosensors with different optical structures, the porous silicon microcavity psm offers very high sensitivity 16,17. Chapter 7 optical devices based on porous silicon multilayers. Conjugated polymers entrapped in porous silicon microcavity have been studied as optical sensors for low volatility explosives such as trinitrotoluene. Increasing the thickness of the central active layer introduces multiple narrow peaks in the luminescence spectrum. Photonic crystal sensors based on porous silicon mdpi. The emission peak position is completely tunable by changing the properties of the central layer. Vertical hybrid microcavity based on a polymer layer sandwiched between porous silicon photonic crystals f. Porous silicon microcavity resonators possess the unique characteristics of line narrowing and luminescence enhancement. Under the irradiation of a hene laser, the surface images of the psi array cells with the microcavity structure were obtained by the digital imaging equipment, whereas the refractive index change of each array.
As porous silicon show pl emission in the transparent region of the biological tissue, they can be used as active particles for sensing applications. Study on the distribution of biomolecules in different. Photon losses in porous silicon microcavities, physica. In our work, the temperature of the solution and the velocity of the air stream flowing through the solution have been used to control the response of the sensor for. Porous silicon microcavity was prepared by forming two rugate mirrors separated by central layer. Lanthanide luminescence enhancements in porous silicon. Porous silicon ps is a material used in the manufacture of onedimensional photonic crystals. A porous silicon microcavity psmc sensor has been made for vapors of solvent solutions, and a method has been developed in order to obtain simultaneous determination of two volatile substances with different concentrations. Among porous silicon biosensors with different optical structures, the porous silicon microcavity psm offers very high sensitivity 16,17. Monitoring penetration of ethanol in a porous silicon. Pdf a microcavity based on a porous silicon multilayer. A vapor sensor based on a porous silicon microcavity for the determination of solvent solutions porous silicon. Fluorescent polymer porous silicon microcavity devices for explosive detection i.
Roomtemperature lowthreshold lasing from monolithically. Hydatid detection using the nearinfrared transmission. Pdf photoluminescence of cdsezns quantum dots in a. Effect of silicon crystal size on photoluminescence. With optimized parameters and the optimized sequence structure from simulations, proper porous silicon microcavity psm based on silicononinsulator soi. Transferprinting assembly is a pickandplace method that uses an elastomeric stamp, commonly polydimethylsiloxane pdms. Porous silicon optical microcavity biosensor on siliconon. Over the last decade, various research groups have demonstrated the use of the 1d pbg psi microcavity for applications in biological and chemical optical sensors 411. Lightharvesting bionanomaterial using porous silicon and photosynthetic reaction center porous silicon microcavity psimc structures were used to immobilize the photosynthetic reaction center rc purified from the purple bacterium rhodobacter sphaeroides r26. Porous silicon colloids have unique properties because of the following. Electrochemical etching of silicon can generate porous silicon where porosity is. Each rugate mirror was etched using a sinusoidal current density signal oscillating between 5 ma cm. Gergely optical characterization of porous silicon. Detection of mmp 8 via porous silicon microcavity devices functionalized.
The second microcavity structure is constructed with a larger su8 thickness that shifts the microcavity resonance to the tail of the gaas emission spectrum. Study on the distribution of biomolecules in different layers. Design of porous silicon dbr is a complex one and requires appropriate control in optical parameters of its constituent layers. Dengue ns1 detection used chemically modified porous.
Pdf a vapor sensor based on a porous silicon microcavity. Detection and light enhancement of glucose oxidase. Fluorescent polymerporous silicon microcavity devices for explosive detection i. The resonance wavelength redshifts after species are added to the psi matrix 16 figure 1. The fluorescence spectra of entrapped polymers were modulated by the microcavity via a spectral hole that matches the resonance peak of the microcavity reflectance. Exposure of the porous silicon microcavity containing entrapped polymer to explosives vapor results in a red shift of the resonance peak and the spectral hole, accompanied by the quenching of the. Metal nanoparticles npspsimc enhanced fluorescence substrates were prepared by the electrostatic adherence of au nps that were distributed. Design, analysis and optimization of porous silicon microcavity. Metal nanoparticlesporous silicon microcavity enhanced. Porous silicon resonant microcavity biosensor for matrix. Fluorescent polymerporous silicon microcavity devices for. Localization of light in the vicinity of a microcavity layer incorporated in a photonic crystal of porous silicon leads to 150fold enhancement of the second harmonic intensity and 30fold enhancement of raman scattering around the microcavity mode. Nov 01, 2005 photon losses in porous silicon microcavities photon losses in porous silicon microcavities rubo, yuri g solano, m.
These structures are based on a planar resonator formed by two higlectance mirrors separated by a thin active optical spacer. The psimc platform was modified for optimized luminescence enhancement which encompassed changing. In order to simulate and predict the optical properties of the microcavity, the transfer matrix. The optical devices presented here are dbrs, microcavities and omnidirectional mirrors. Nearfield spectroscopy of porous silicon microcavity samples. Porous silicon multilayer mirrors and microcavity resonators for optoelectronic applications volume 536 s. Chapter 2 fundamentals of porous silicon and applications. Lightharvesting bionanomaterial using porous silicon and.
However, oxidation is required to stabilize the asanodized porous silicon film. In this paper, we demonstrate the detection of europiumcomplexlabeled streptavidin in a porous silicon microcavity psimc via luminescence enhancement. Optical characterization of porous silicon microcavities. In this paper, the covalent immobilization and luminescence enhancement of a europium euiii complex in a porous silicon psi layer with a microcavity psimc structure are demonstrated. Pbg resultant structure is a porous silicon microcavity psm or a microcavity between two mirrors. Timeresolved spectroscopy of ethanol evaporation on free. Optical characterization of single layer samples showed series of interference fringes. A nanoporous silicon 1d photonic band gap microcavity as. Nano porous silicon microcavity sensor for determination. Results and discussion printing hybrid porous silicon microcavities. It results in a unique pl spectrum with a high quantum. A vapor sensor based on a porous silicon microcavity for the determination of solvent solutions. Pdf the present paper reports the study of a porous silicon based microcavity for a potential chemical sensing application using.
The main objective of this work is to develop an optical sensor to detect the level of adulteration in a fuel sample using a porous silicon microcavity psmc. In order to estimate the refractive index of the microcavity layers, several individual porous. These properties are studied in both experimentation and simulation. Porous sisio2 uv microcavities are used to modulate a broad responsivity photodetector gvgrt10gd with a detection range from 300 to 510 nm. These results support that our oxidation process is very advantageous to obtain complex photonic structures in the uv region. A microcavity based on a porous silicon multilayer iopscience. A nanoporous silicon 1d photonic band gap microcavity as a. Porous sisio 2 based uv microcavities scientific reports nature. A quantum derivation of the shape of the resonant transmittance peak for the general case is presented and then we analyze the effect of rayleigh scattering of light on the disordered structure of porous silicon in details. We present a new result for the wavelengthselective characteristics of a 1d photonic microcavity based on porous silicon. Pdf porous silicon optical microcavity for chemical sensing.
Nanoporous silicon microcavity sensor for detection of organic solvents in the gasoline the basic characteristics of the porous silicon microcavity psm and the resonant wavelength shift caused by the ambient refractive index n were determined experimentally by using a series of liquids with known refractive indices. A microcavity is composed of a fabry perot cavity sandwiched between two bragg reflectors. Porous silicon microcavity, xrd, raman, reflectance, rugate filters. Optical characterization of porous silicon microcavities for. The most commonly used method for the detection of. The ptype silicon substrates yield the most favorable porous silicon morphology. Feb 23, 2018 a porous silicon microcavity psimc with resonant peak wavelength of 635 nm was fabricated by electrochemical etching. They were trying to develop an electrochemical method to machine silicon wafers for use in microelectronic circuits. Photoluminescence of cdsezns quantum dots in a porous silicon microcavity dmitriy s. The design parameters of the microcavity were optimized to. The benefit of adding a multilayer mirror below a luminescent film of porous silicon is to significantly reduce the amount of light loss to the silicon substrate and increase the light output. The microcavity structure contains an active porous silicon layer sandwiched between two distributed porous silicon bragg reflectors. Porous sisio 2 based uv microcavities scientific reports.
A vapor sensor based on a porous silicon microcavity for. Pdf the properties and preliminar applications of poroussilicon psi microcavities are here reported. This paper proposes a labelfree and spectrometerfree method for biological detection with high detecting resolution. Abstract we study theoretically the optical losses in a microcavity made of porous silicon. Transferprinting of tunable porous silicon microcavities. Photoluminescence studies of porous silicon microcavities. Gergely optical characterization of porous silicon microcavities for glucose oxidase biosensing, proc. Photon losses in porous silicon microcavities, physica status.
Three different pore diameter ps samples were prepared by electrochemical etching in hfbased solutions. May 08, 2008 8 may 2008 optical characterization of porous silicon microcavities for glucose oxidase biosensing. Porous silicon microcavities for biosensing applications. Based on the above method, labelfree eightbase pair.
This composite device, seeks to leverage the versatile material properties of both hydrogels and porous silicon, the latter of which is produced by electrochemical dissolution of. The pl emission of a single porous silicon colloid see figure figure5 5 is strongly coupled to the resonating modes of the microcavity. A porous silicon microcavity psimc with resonant peak wavelength of 635 nm was fabricated by electrochemical etching. Bragg reflectors brs 1,2, microcavities mcs 3,4, rugate filters 5,6, and waveguides 7. Photoluminescence of cdsezns quantum dots in a porous. The psimc platform was modified for optimized luminescence enhancement which encompassed changing the pore size of the microcavity to ensure molecular inf. Porous silicon material has taken more and more attention in recent years for biosensing applications and some useful results have been obtained. Pdf impact of thermal oxidation on the structural and. Fluorescent polymerporous silicon microcavity devices.
The psimc platform was modified for optimized luminescence enhancement which encompassed changing the pore size of the microcavity to ensure molecular infiltration and adjusting the optical. In this work, based on simulations to obtain appropriate optical properties of a porous silicon microcavity psm, we successfully fabricated a highly efficient psm on soi wafer by electrochemical etching for dna detection at optical wavelength 1555. Biomolecule detection in porous silicon based microcavities. The crosssectional sem images of porous silicon microcavity having a slight difference in thickness of the top and bottom mirror. The alkynependant arm of the euiii complex was covalently immobilized on the azidemodified surface via ligandassisted click chemistry. In this paper, we report the feasibility of applying porous silicon microcavity biosensor in a novel and relatively rapid serodiagnostic approach. The optical response of a microcavity has been studied under different. The experimental results show that the elaborated porous silicon photonic microcavities have the wavelengthselective property in a. With optimized parameters and the optimized sequence structure from simulations, proper porous silicon microcavity psm based on siliconon insulator soi. Porous silicon based bragg reflect ors and fabryperot interference filters for photonic applications dharmalingam mangaiyarkarasi a, mark b h breese a, ow yueh sheng a, kambiz ansari a chellappan vijila b, and daniel blackwood c acentre for ion beam applications, 2 sc ience drive 3, department of physics, national university of singapore, singapore 117542.
1018 373 620 1022 79 558 1567 119 1069 870 534 449 1540 961 1490 494 361 1268 1435 408 377 1355 924 1214 377 501 1246 1090 828 735 55 663 1237 1000 426